What is Faraday's First Law
Michael Faraday wrote in his "Experimental Studies on Electricity" in 1821:
|§ 360||"The general conclusion that I believe must be drawn from the sum of facts is that all electricity, from whatever source, is essentially identical."|
(Note: This refers to "atmospheric electricity", "frictional electricity", "galvanic electricity", "thermoelectricity" and "induction electricity", which were examined in the previous paragraphs.)
|§ 361||"After I believed the identity had been sufficiently established, my next endeavor was to obtain a common measure or known quantity relation between that excited by an electrifying machine and the electricity of a voltaic pillar."|
Faraday finds that "the chemical as well as the magnetic force is directly proportional to the absolute quantity of the electricity passed through."
|§ 504||"The sum of the chemical composition is constant for every cross-section of a conductor subject to decomposition and of uniform nature, whatever the distance between the poles or the cross-section may be."|
|§ 505||"For a constant quantity of electricity, for every conductor subject to decomposition, let it consist of water, salt solutions, acids, molten bodies, etc., the amount of electrochemical action is also a constant quantity. what we call electric current [...] is present [...] as the axis of a total force consisting of opposing, directed forces ".|
"The chemical force of an electric current is directly proportional to the absolute amount of electricity passed through."
|§ 821||provides the proportionality factor from experiments using equivalence masses:|
"The results obtained with any substance do not merely agree with one another, but also with those obtained with other substances, so that all combine together in a series of fixed electrochemical actions."
|§ 836||"Electrochemical equivalents are the same as ordinary chemical equivalents."|
This provides the above proportionality factor by putting the equivalent mass and charge in relation to one another. The second Faraday's law reads in the usual formulation: "The same amounts of electricity separate different substances in the ratio of their chemical equivalent masses."
Both laws can be summarized:
This expresses the preservation of charge and mass during electrolysis - however, Faraday's interpretation was far from being. He just concluded:
|§ 869||"The equivalent weights of bodies are simply those quantities of the same which contain equal quantities of electricity [...]; it is the electricity that determines the equivalent number [...]. But if we accept atomic theory and its terminology, it is the atoms of bodies which are equivalent in their ordinary chemical action and which are naturally associated with equal amounts of electricity. But I must confess that I am suspicious of the term atom, for it is very easy to speak of atoms, but very difficult. To get a clear idea of their nature, especially when composite bodies are involved. "|
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